Table A-1 of Subpart A of Part 98 - Global Warming Potentials

In addition to the global warming potentials (GWPs) from Table A-1 that should be used for reporting for Reporting Year (RY) 2014 onwards, the tables below include the GWPs that should be used for prior Reporting Years (RY2013 and RY2010-12). Table A-1 includes GWPs for the following classes of compounds:

 

Chemical-Specific GWPs

Name

CAS No

Chemical

formula

GWPs for Reporting Years 2014 and later

GWPs for Reporting Year 2013

GWPs for Reporting Years 2010, 2011, and 2012

Carbon dioxide 

124–38–9

CO2  

1

1

1

Methane 

74–82–8

CH4  

25

25

21

Nitrous oxide 

10024–97–2

N2

298

298

310

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Fully Fluorinated GHGs 

Name

CAS No.

Chemical formula

GWPs for Reporting Years 2014 and later

GWPs for Reporting Year 2013

GWPs for Reporting Years 2010, 2011, and 2012

Sulfur hexafluoride 

2551–62–4

SF6  

22,800

22,800

23,900

Trifluoromethyl sulphur pentafluoride 

373–80–8

SF5CF3  

17,700

17,700

17,700

Nitrogen trifluoride 

7783–54–2

NF3 

17,200

17,200

17,200

PFC–14 (Perfluoromethane) 

75–73–0

CF4  

7,390

7,390

6,500

PFC–116 (Perfluoroethane) 

76–16–4

C2F6

12,200

12,200

9,200

PFC–218 (Perfluoropropane) 

76–19–7

C3F8

8,830

8,830

7,000

Perfluorocyclopropane 

931–91–9

C–C3F6  

17,340

17,340

17,340

PFC–3–1–10 (Perfluorobutane) 

355–25–9

C4F10

8,860

8,860

7,000

PFC–318 (Perfluorocyclobutane) 

115–25–3

C–C4F8

10,300

10,300

8,700

PFC–4–1–12 (Perfluoropentane) 

678–26–2

C5F12

9,160

9,160

7,500

PFC–5–1–14 (Perfluorohexane, FC–72) 

355–42–0

C6F14

9,300

9,300

7,400

PFC–6–1–12 

335–57–9

C7F16; CF3(CF2)5CF3

7,820

-

-

PFC–7–1–18 

307–34–6

C8F18; CF3(CF2)6CF3

7,620

-

-

PFC–9–1–18 

306–94–5

C10F18  

7,500

7,500

7,500

PFPMIE (HT–70) 

NA

CF3OCF(CF3)CF2OCF2OCF3  

10,300

10,300

10,300

Perfluorodecalin (cis) 

60433–11–6

Z–C10F18

7,236

-

-

Perfluorodecalin (trans) 

60433–12–7

E–C10F18

6,288

-

-

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Saturated Hydrofluorocarbons (HFCs) With Two or Fewer Carbon-Hydrogen Bonds 

Name

CAS No.

Chemical formula

GWPs for Reporting Years 2014 and later

GWPs for Reporting Year 2013

GWPs for Reporting Years 2010, 2011, and 2012

HFC–23 

75–46–7

CHF3  

 14,800

14,800

11,700

HFC–32 

75–10–5

CH2F2 

 675

675

650

HFC–125 

354–33–6

C2HF5  

 3,500

3,500

2,800

HFC–134 

359–35–3

C2H2F4  

 1,100

1,100

1,000

HFC–134a 

811–97–2

CH2FCF3  

 1,430

1,430

1300

HFC–227ca 

2252–84–8

CF3CF2CHF2 

 2,640

-

-

HFC–227ea 

431–89–0

C3HF7  

 3,220

3,220

2,900

HFC–236cb 

677–56–5

CH2FCF2CF3  

1,340

1,340

1,340

HFC–236ea 

431–63–0

CHF2CHFCF3  

1,370

1,370

1,370

HFC–236fa 

690–39–1

C3H2F6  

 9,810

9,810

6,300

HFC–329p 

375–17–7

CHF2CF2CF2CF3  

 2,360

-

-

HFC–43–10mee 

138495–42–8

CF3CFHCFHCF2CF3  

 1,640

1,640

1,300

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Saturated Hydrofluorocarbons (HFCs) With Three or More Carbon-Hydrogen Bonds 

Name

CAS No.

Chemical formula

GWPs for Reporting Years 2014 and later

GWPs for Reporting Year 2013

GWPs for Reporting Years 2010, 2011, and 2012

HFC–41 

593–53–3

CH3

 92

92

150

HFC–143 

430–66–0

C2H3F3  

 353

353

300

HFC–143a 

420–46–2

C2H3F3  

 4,470

4,470

3,800

HFC–152 

624–72–6

CH2FCH2

53

53

53

HFC–152a 

75–37–6

CH3CHF2 

 124

124

140

HFC–161 

353–36–6

CH3CH2

12

12

12

HFC–245ca 

679–86–7

C3H3F5  

 693

693

560

HFC–245cb 

1814–88–6

CF3CF2CH3  

 4,620

-

-

HFC–245ea 

24270–66–4

CHF2CHFCHF2 

 235

-

-

HFC–245eb 

431–31–2

CH2FCHFCF3  

 290

-

-

HFC–245fa 

460–73–1

CHF2CH2CF3  

1,030

1,030

1,030

HFC–263fb 

421–07–8

CH3CH2CF3  

 76

-

-

HFC–272ca 

420–45–1

CH3CF2CH3  

 144

-

-

HFC–365mfc 

406–58–6

CH3CF2CH2CF3  

794

794

794

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Saturated Hydrofluoroethers (HFEs) and Hydrochlorofluoroethers (HCFEs) With One Carbon-Hydrogen Bond 

Name

CAS No.

Chemical formula

GWPs for Reporting Years 2014 and later

GWPs for Reporting Year 2013

GWPs for Reporting Years 2010, 2011, and 2012

HFE–125 

3822–68–2

CHF2OCF3  

14,900

14,900

14,900

HFE–227ea 

2356–62–9

CF3CHFOCF3  

1,540

1,540

1,540

HFE–329mcc2 

134769–21–4

CF3CF2OCF2CHF2 

919

919

919

HFE–329me3 

428454–68–6

CF3CFHCF2OCF3  

4,550

-

-

1,1,1,2,2,3,3-Heptafluoro-3-(1,2,2,2-tetrafluoroethoxy)-propane 

3330–15–2

CF3CF2CF2OCHFCF3  

6,490

-

-

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Saturated HFEs and HCFEs With Two Carbon-Hydrogen Bonds 

Name

CAS No.

Chemical formula

GWPs for Reporting Years 2014 and later

GWPs for Reporting Year 2013

GWPs for Reporting Years 2010, 2011, and 2012

HFE–134 (HG–00) 

1691–17–4

CHF2OCHF2 

6,320

6,320

6,320

HFE–236ca 

32778–11–3

CHF2OCF2CHF2 

 4,240

-

-

HFE–236ca12 (HG–10) 

78522–47–1

CHF2OCF2OCHF2 

2,800

2,800

2,800

HFE–236ea2 (Desflurane) 

57041–67–5

CHF2OCHFCF3  

989

989

989

HFE–236fa

20193–67–3

CF3CH2OCF3  

487

487

487

HFE–338mcf2 

156053–88–2

CF3CF2OCH2CF3  

552

552

552

HFE–338mmz1 

26103–08–2

CHF2OCH(CF3)2 

380

380

380

HFE–338pcc13 (HG–01) 

188690–78–0

CHF2OCF2CF2OCHF2 

1,500

1,500

1,500

HFE–43–10pccc (H-Galden 1040x, HG–11) 

E1730133

CHF2OCF2OC2F4OCHF2 

1,870

1,870

1,870

HCFE–235ca2 (Enflurane) 

13838–16–9

CHF2OCF2CHFCl 

 583

 

 

HCFE–235da2 (Isoflurane) 

26675–46–7

CHF2OCHClCF3  

350

350

350

HG–02 

205367–61–9

HF2C-(OCF2CF2)2-OCF2

 3,825

-

-

HG–03 

173350–37–3

HF2C-(OCF2CF2)3-OCF2H  

 3,670

-

-

HG–20 

249932–25–0

HF2C-(OCF2)2--OCF2H  

 5,300

-

-

HG–21 

249932–26–1

HF2C-OCF2CF2OCF2OCF2O–CF2

 3,890

-

-

HG–30 

188690–77–9

HF2C-(OCF2)3--OCF2H  

 7,330

-

-

1,1,3,3,4,4,6,6,7,7,9,9,10,10,12,12,13,13,15,15-eicosafluoro-2,5,8,11,14-Pentaoxapentadecane

173350–38–4

HCF2O(CF2CF2O)4CF2

 3,630

-

-

 

1,1,2-Trifluoro-2-(trifluoromethoxy)-ethane 

84011–06–3

CHF2CHFOCF3  

 1,240

-

-

Trifluoro(fluoromethoxy)methane 

2261–01–0

CH2FOCF3  

 751

-

-

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Saturated HFEs and HCFEs With Three or More Carbon-Hydrogen Bonds 

Name

CAS No.

Chemical formula

GWPs for Reporting Years 2014 and later

GWPs for Reporting Year 2013

GWPs for Reporting Years 2010, 2011, and 2012

HFE–143a 

421–14–7

CH3OCF3  

756

756

756

HFE–245cb2 

22410–44–2

CH3OCF2CF3  

708

708

708

HFE–245fa1 

84011–15–4

CHF2CH2OCF3  

286

286

286

HFE–245fa2 

1885–48–9

CHF2OCH2CF3  

659

659

659

HFE–254cb2 

425–88–7

CH3OCF2CHF2 

359

359

359

HFE–263fb2 

460–43–5

CF3CH2OCH3  

11

11

11

HFE–263m1; R–E–143a 

690–22–2

CF3OCH2CH3  

29

-

-

HFE–347mcc3 (HFE–7000) 

375–03–1

CH3OCF2CF2CF3  

575

575

575

HFE–347mcf2 

171182–95–9

CF3CF2OCH2CHF2 

374

374

374

HFE–347mmy1 

22052–84–2

CH3OCF(CF3)2 

343

343

343

HFE–347mmz1 (Sevoflurane) 

28523–86–6

(CF3)2CHOCH2

216

345

345

HFE–347pcf2 

406–78–0

CHF2CF2OCH2CF3  

580

580

580

HFE–356mec3 

382–34–3

CH3OCF2CHFCF3  

101

101

101

HFE–356mff2 

333–36–8

CF3CH2OCH2CF3  

17

-

-

HFE–356mmz1 

13171–18–1

(CF3)2CHOCH3 

27

27

27

HFE–356pcc3 

160620–20–2

CH3OCF2CF2CHF2 

110

110

110

HFE–356pcf2 

50807–77–7

CHF2CH2OCF2CHF2 

265

265

265

HFE–356pcf3 

35042–99–0

CHF2OCH2CF2CHF2 

502

502

502

HFE–365mcf2 

22052–81–9

CF3CF2OCH2CH3  

58

-

-

HFE–365mcf3 

378–16–5

CF3CF2CH2OCH3  

11

11

11

HFE–374pc2 

512–51–6

CH3CH2OCF2CHF2 

557

557

557

HFE–449s1 (HFE–7100) Chemical blend 

163702–07–6

163702–08–7

C4F9OCH3 

(CF3)2CFCF2OCH3

297

297

297

HFE–569sf2 (HFE–7200) Chemical blend 

163702–05–4

163702–06–5

C4F9OC2H5  

(CF3)2CFCF2OC2H5

59

59

59

HG’-01 

73287–23–7

CH3OCF2CF2OCH3  

 222

-

-

HG’-02 

485399–46–0

CH3O(CF2CF2O)2CH3  

 236

-

-

HG’-03 

485399–48–2

CH3O(CF2CF2O)3CH3 

 221

-

-

Difluoro(methoxy)methane 

359–15–9

CH3OCHF2 

 144

-

-

2-Chloro-1,1,2-trifluoro-1-methoxyethane 

425–87–6

CH3OCF2CHFCl 

 122

-

-

1-Ethoxy-1,1,2,2,3,3,3-heptafluoropropane 

22052–86–4

CF3CF2CF2OCH2CH3  

 61

-

-

2-Ethoxy-3,3,4,4,5-pentafluorotetrahydro-2,5-bis[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]-furan

920979–28–8

C12H5F19O2 

 56

-

-

1-Ethoxy-1,1,2,3,3,3-hexafluoropropane 

380–34–7

CF3CHFCF2OCH2CH3 

 23

-

-

Fluoro(methoxy)methane 

460–22–0

CH3OCH2

 13

-

-

1,1,2,2-Tetrafluoro-3-methoxy-propane; Methyl 2,2,3,3-tetrafluoro propyl ether

60598–17–6

CHF2CF2CH2OCH3  

 0.5

-

-

1,1,2,2-Tetrafluoro-1-(fluoromethoxy)ethane 

37031–31–5

CH2FOCF2CF2

 871

-

-

Difluoro(fluoromethoxy)methane 

461–63–2

CH2FOCHF2 

 617

-

-

Fluoro(fluoromethoxy)methane 

462–51–1

CH2FOCH2

 130

-

-

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Fluorinated Formates 

Name

CAS No.

Chemical formula

GWPs for Reporting Years 2014 and later

GWPs for Reporting Year 2013

GWPs for Reporting Years 2010, 2011, and 2012

Trifluoromethyl formate 

85358–65–2

HCOOCF3  

 588

-

-

Perfluoroethyl formate 

313064–40–3

HCOOCF2CF3  

 580

-

-

1,2,2,2-Tetrafluoroethyl formate 

481631–19–0

HCOOCHFCF3  

 470

-

-

Perfluorobutyl formate 

197218–56–7

HCOOCF2CF2CF2CF3  

 392

-

-

Perfluoropropyl formate 

271257–42–2

HCOOCF2CF2CF3  

 376

-

-

1,1,1,3,3,3-Hexafluoropropan-2-yl formate 

856766–70–6

HCOOCH(CF3)2 

 333

-

-

2,2,2-Trifluoroethyl formate 

32042–38–9

HCOOCH2CF3  

 33

-

-

3,3,3-Trifluoropropyl formate 

1344118–09–7

HCOOCH2CH2CF3  

 17

-

-

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Fluorinated Acetates 

Name

CAS No.

Chemical formula

GWPs for Reporting Years 2014 and later

GWPs for Reporting Year 2013

GWPs for Reporting Years 2010, 2011, and 2012

Methyl 2,2,2-trifluoroacetate 

431–47–0

CF3COOCH3  

 52

-

-

1,1-Difluoroethyl 2,2,2-trifluoroacetate 

1344118–13–3

CF3COOCF2CH3  

 31

-

-

Difluoromethyl 2,2,2-trifluoroacetate 

2024–86–4

CF3COOCHF2 

 27

-

-

2,2,2-Trifluoroethyl 2,2,2-trifluoroacetate 

407–38–5

CF3COOCH2CF3  

 7

-

-

Methyl 2,2-difluoroacetate 

433–53–4

HCF2COOCH3  

 3

-

-

Perfluoroethyl acetate 

343269–97–6

CH3COOCF2CF3  

 2.1

-

-

Trifluoromethyl acetate 

74123–20–9

CH3COOCF3  

 2.0

-

-

Perfluoropropyl acetate 

1344118–10–0

CH3COOCF2CF2CF3  

 1.8

-

-

Perfluorobutyl acetate 

209597–28–4

CH3COOCF2CF2CF2CF3  

 1.6

-

-

Ethyl 2,2,2-trifluoroacetate 

383–63–1

CF3COOCH2CH3  

 1.3

-

-

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Carbonofluoridates 

Name

CAS No.

Chemical formula

GWPs for Reporting Years 2014 and later

GWPs for Reporting Year 2013

GWPs for Reporting Years 2010, 2011, and 2012

Methyl carbonofluoridate 

1538–06–3

FCOOCH3  

95

-

-

1,1-Difluoroethyl carbonofluoridate 

1344118–11–1

FCOOCF2CH3  

27

-

-

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Fluorinated Alcohols Other Than Fluorotelomer Alcohols 

Name

CAS No.

Chemical formula

GWPs for Reporting Years 2014 and later

GWPs for Reporting Year 2013

GWPs for Reporting Years 2010, 2011, and 2012

Bis(trifluoromethyl)-methanol 

920–66–1

(CF3)2CHOH 

195

195

195

(Octafluorotetramethy-lene) hydroxymethyl group 

NA

X-(CF2)4CH(OH)-X 

73

73

73

2,2,3,3,3-Pentafluoropropanol 

422–05–9

CF3CF2CH2OH 

42

42

42

2,2,3,3,4,4,4-Heptafluorobutan-1-ol 

375–01–9

C3F7CH2OH 

 25

-

-

2,2,2-Trifluoroethanol 

75–89–8

CF3CH2OH 

 20

-

-

2,2,3,4,4,4-Hexafluoro-1-butanol 

382–31–0

CF3CHFCF2CH2OH 

 17

-

-

2,2,3,3-Tetrafluoro-1-propanol 

76–37–9

CHF2CF2CH2OH 

 13

-

-

2,2-Difluoroethanol 

359–13–7

CHF2CH2OH 

 3

-

-

2-Fluoroethanol 

371–62–0

CH2FCH2OH 

 1.1

-

-

4,4,4-Trifluorobutan-1-ol 

461–18–7

CF3(CH2)2CH2OH 

 0.05

-

-

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Unsaturated Perfluorocarbons (PFCs) 

Name

CAS No.

Chemical formula

GWPs for Reporting Years 2014 and later

GWPs for Reporting Year 2013

GWPs for Reporting Years 2010, 2011, and 2012

PFC–1114; TFE

116–14–3

CF2=CF2; C2F4  

 0.004

-

-

PFC–1216; Dyneon HFP 

116–15–4

C3F6; CF3CF=CF2 

 0.05

-

-

PFC C–1418 

559–40–0

c-C5F8  

 1.97

-

-

Perfluorobut-2-ene 

360–89–4

CF3CF=CFCF3  

 1.82

-

-

Perfluorobut-1-ene 

357–26–6

CF3CF2CF=CF2 

 0.10

-

-

Perfluorobuta-1,3-diene 

685–63–2

CF2=CFCF=CF2 

 0.003

-

-

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Unsaturated Hydrofluorocarbons (HFCs) and Hydrochlorofluorocarbons (HCFCs) 

Name

CAS No.

Chemical formula

GWPs for Reporting Years 2014 and later

GWPs for Reporting Year 2013

GWPs for Reporting Years 2010, 2011, and 2012

HFC–1132a; VF2 

75–38–7

C2H2F2 , CF2=CH2

 0.04

-

-

HFC–1141; VF 

75–02–5

C2H3F ,CH2=CHF 

 0.02

-

-

(E)-HFC–1225ye 

5595–10–8

CF3CF=CHF(E) 

 0.06

-

-

(Z)-HFC–1225ye 

5528–43–8

CF3CF=CHF(Z) 

 0.22

-

-

HCFC-1233zd(E)

102687–65–0

C3H2ClF3; CHCl=CHCF3  

 1.34

-

-

HFC–1234yf; HFO–1234yf 

754–12–1

C3H2F4; CF3CF=CH2 

 0.31

-

-

HFC–1234ze(E) 

1645–83–6

C3H2F4; trans-CF3CH=CHF 

 0.97

-

-

HFC–1234ze(Z) 

29118–25–0

C3H2F4cis-CF3CH=CHF; CF3CH=CHF 

 0.29

-

-

HFC–1243zf; TFP 

677–21–4

C3H3F3, CF3CH=CH2 

 0.12

-

-

(Z)-HFC–1336 

692–49–9

CF3CH=CHCF3 (Z) 

 1.58

-

-

HFC–1345zfc 

374–27–6

C2F5CH=CH2 

 0.09

-

-

Capstone 42–U 

19430–93–4

C6H3F9, CF3(CF2)3CH=HH2 

 0.16

-

-

Capstone 62–U 

25291–17–2

C8H3F13, CF3(CF2)5CH=CH2 

 0.11

-

-

Capstone 82–U 

21652–58–4

C10H3F17, CF3(CF2)7CH= CH2 

 0.09

-

-

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Unsaturated Halogenated Ethers 

Name

CAS No.

Chemical formula

GWPs for Reporting Years 2014 and later

GWPs for Reporting Year 2013

GWPs for Reporting Years 2010, 2011, and 2012

PMVE; HFE–216 

1187–93–5

CF3OCF=CF2 

0.17

-

-

Fluoroxene 

406–90–6

CF3CH2OCH=CH2 

0.05

-

-

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Fluorinated Aldehydes 

Name

CAS No.

Chemical formula

GWPs for Reporting Years 2014 and later

GWPs for Reporting Year 2013

GWPs for Reporting Years 2010, 2011, and 2012

3,3,3-Trifluoro-propanal 

460–40–2

CF3CH2CHO 

0.01

-

-

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Fluorinated Ketones 

Name

CAS No.

Chemical formula

GWPs for Reporting Years 2014 and later

GWPs for Reporting Year 2013

GWPs for Reporting Years 2010, 2011, and 2012

Novec 1230 (perfluoro (2-methyl-3-pentanone)) 

756–13–8

CF3CF2C(O)CF(CF3)2 

0.1

-

-

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Fluorotelomer Alcohols 

Name

CAS No.

Chemical formula

GWPs for Reporting Years 2014 and later

GWPs for Reporting Year 2013

GWPs for Reporting Years 2010, 2011, and 2012

3,3,4,4,5,5,6,6,7,7,7-Undecafluoroheptan-1-ol 

185689–57–0

CF3(CF2)4CH2CH2OH 

 0.43

-

-

3,3,3-Trifluoropropan-1-ol 

2240–88–2

CF3CH2CH2OH 

 0.35

-

-

3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-Pentadecafluorononan-1-ol 

755–02–2

CF3(CF2)6CH2CH2OH 

 0.33

-

-

3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Nonadecafluoroundecan-1-ol

87017–97–8

CF3(CF2)8CH2CH2OH 

 0.19

-

-

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Fluorinated GHGs With Carbon-Iodine Bond(s) 

Name

CAS No.

Chemical formula

GWPs for Reporting Years 2014 and later

GWPs for Reporting Year 2013

GWPs for Reporting Years 2010, 2011, and 2012

Trifluoroiodomethane 

2314–97–8

CF3

0.4

-

-

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Other Fluorinated Compounds 

Name

CAS No.

Chemical formula

GWPs for Reporting Years 2014 and later

GWPs for Reporting Year 2013

GWPs for Reporting Years 2010, 2011, and 2012

Dibromodifluoromethane (Halon 1202) 

75–61–6

CBr2F2 

231

-

-

2-Bromo-2-chloro-1,1,1-trifluoroethane (Halon-2311/Halothane) 

151–67–7

CHBrClCF3  

41

-

-

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Default GWPs for Compounds for Which Chemical-Specific GWPs Are Not Listed Above

Fluorinated GHG Group*

Global warming potential (100 yr.)

Fully fluorinated GHGs 

10,000

Saturated hydrofluorocarbons (HFCs) with 2 or fewer carbon-hydrogen bonds 

3,700

Saturated HFCs with 3 or more carbon-hydrogen bonds  

930

Saturated hydrofluoroethers (HFEs) and hydrochlorofluoroethers (HCFEs) with 1 carbon-hydrogen bond 

5,700

Saturated HFEs and HCFEs with 2 carbon-hydrogen bonds 

2,600

Saturated HFEs and HCFEs with 3 or more carbon-hydrogen bonds 

270

Fluorinated formates 

350

Fluorinated acetates, carbonofluoridates, and fluorinated alcohols other than fluorotelomer alcohols 

30

Unsaturated perfluorocarbons (PFCs), unsaturated HFCs, unsaturated hydrochlorofluorocarbons (HCFCs), unsaturated halogenated ethers, unsaturated halogenated esters, fluorinated aldehydes, and fluorinated ketones 

1

Fluorotelomer alcohols 

1

Fluorinated GHGs with carbon-iodine bond(s) 

1

Other fluorinated GHGs 

2,000

* For electronics manufacturing (as defined in § 98.90), the term "fluorinated GHGs" in the definition of each fluorinated GHG group in § 98.6 shall include fluorinated heat transfer fluids (as defined in § 98.98), whether or not they are also fluorinated GHGs.

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